The coordination (hydration) of rare earth ions in aqueous c…
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- DOI 10.1063/1.439895
- OpenAlex ID W2050459477
- Type Article
- Language EN
- Published 01 Jul 1980
- Volume 73 (1)
- Pages 442–450
- Source The Journal of Chemical Physics
- Publisher American Institute of Physics
- FWCI 7.94
- Countries 1
- Institutions 2
- Added 10 Oct 2025
- Updated 24 Oct 2026
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The coordination (hydration) of rare earth ions in aqueous chloride solutions from x-ray diffraction. III. SmCl3, EuCl3, and series behavior
Article 1980 EN
The inner sphere water coordination of Sm3+ and Eu3+ in concentrated (3.23 m) aqueous chloride solutions was obtained from x-ray diffraction measurements at 25 °C. The average water coordination is 8.8 for Sm3+ and 8.3 for Eu3+. The average RE3+–H2O distances are 2.474 Å for Sm3+ and 2.450 Å for Eu3+. The average RE3+⋅⋅⋅Cl− ion pair distances occur near 4.9 Å. A careful examination of the x-ray di…
276
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2
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7.94
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2 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | A. Habenschuss | Iowa State University (US) Ames National Laboratory (US) | — |
| 2 | Frank H. Spedding | Iowa State University (US) Ames National Laboratory (US) | — |
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