EXAFS analysis of uranium(IV) and thorium(IV) complexes in c…

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2011
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  • DOI 10.1524/rcpr.2011.0030
  • OpenAlex ID W240159348
  • Type Article
  • Language EN
  • Published 01 Sep 2011
  • Volume 1 (1)
  • Pages 161–165
  • Source Proceedings in Radiochemistry
  • Publisher R. Oldenbourg Verlag
  • Countries 1
  • Institutions 4
  • Added 10 Oct 2025
  • Updated 13 Oct 2026
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EXAFS analysis of uranium(IV) and thorium(IV) complexes in concentrated CaCl2 solutions

Article 2011 EN Diamond

Abstract The coordination of U4+ and Th4+ in concentrated CaCl2 solutions is studied by U and Th L III edge extended X-ray absorption fine structure (EXAFS) spectroscopy. With the decrease of concentration of CaCl2 from 6.9 to 4 M, the Cl− ion coordination number N Cl in the U4+ coordination sphere decreases from 3.4 to 1.3, while the hydration number N O increases from 4.5 to 6.7. The combined co…

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8 authors
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1 Akihiro Uehara Institute for Integrated Radia… (JP)
2 Toshiyuki Fujii Kyoto University (JP) Institute for Integrated Radia… (JP)
3 Haruaki Matsuura —
4 N. Sato Japan Atomic Energy Agency (JP) Advanced Science Research Cent… (JP)
5 Takayuki Nagai Japan Atomic Energy Agency (JP)
6 Kenjiro Minato — —
7 H. Yamana — —
8 Yoshihiro Okamoto —

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