Ligand-Controlled Regioselective Pd-Catalyzed Diamination of…

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Ligand-Controlled Regioselective Pd-Catalyzed Diamination of Alkenes

Article 2020 EN

A ligand-controlled system has been disclosed for the regioselective palladium-catalyzed diamination of unactivated alkenes, which provides an easy access to a variety of amino-functionalized piperidines and pyrrolidines. The steric hindrance of ligands controlled the regioselectivtities of products. 6- Endo diamination occurred with less sterically hindered quinox ligand to afford 3-aminopiperidi…

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5 authors
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1 Xiaojian Liu Jiangxi Normal University (CN)
2 Chuanqi Hou Chinese Academy of Sciences (CN) Shanghai Institute of Organic … (CN) +1 —
3 Yiyuan Peng Corresponding Jiangxi Normal University (CN)
4 Pinhong Chen Corresponding Chinese Academy of Sciences (CN) Shanghai Institute of Organic … (CN) +1
5 Guosheng Liu Corresponding Chinese Academy of Sciences (CN) Shanghai Institute of Organic … (CN) +1

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