Free Radical Formation in the Peroxynitrous Acid (ONOOH)/Per…
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- DOI 10.1021/tx980026s
- PMID https://pubmed.ncbi.nlm.nih.gov/9548793
- OpenAlex ID W2072054201
- Type Article
- Language EN
- Published 20 Mar 1998
- Volume 11 (4)
- Pages 243–246
- Source Chemical Research in Toxicology
- Publisher American Chemical Society
- FWCI 8.19
- Countries 1
- Institutions 1
- Added 24 Jun 2016
- Updated 17 Oct 2026
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Free Radical Formation in the Peroxynitrous Acid (ONOOH)/Peroxynitrite (ONOO-) System
Article 1998 EN
The rate constant of homolysis of peroxynitrite, ONOO-, into O2- and NO was determined to be 0.017 s-1 at 20 degrees C. In combination with other experimental data taken from the literature, this value yields the Gibbs free energy of formation of ONOO-, delta f G o(ONOO-) = 16.6 kcal/mol. On the basis of this result, we conclude that peroxynitrous acid homolyzes to yield nitrogen dioxide (NO2) and…
104
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8.19
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2 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | Gábor Merényi | KTH Royal Institute of Technol… (SE) | — |
| 2 | Johan Lind | KTH Royal Institute of Technol… (SE) |
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