On the Critical Region of a Simple Fluid. II. Scaling-Law Eq…

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1971
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  • DOI 10.1063/1.1675016
  • OpenAlex ID W2013354582
  • Type Article
  • Language EN
  • Published 01 Feb 1971
  • Volume 54 (3)
  • Pages 895–897
  • Source The Journal of Chemical Physics
  • Publisher American Institute of Physics
  • FWCI 1.24
  • Countries 1
  • Institutions 1
  • Added 24 Jun 2016
  • Updated 02 Oct 2026
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On the Critical Region of a Simple Fluid. II. Scaling-Law Equation of State

Article 1971 EN

The scaling-law equation of state is used to illustrate some consequences of the elementary index inequalities β + γ− > 1 > α− + β. It is shown that (∂2P / ∂T2)V evaluated on the phase boundary below Tc from the homogeneous-phase side diverges with index (α + β), where α is the (scaling-law) index for CV=Vc. Also, it is shown that CP=Pc diverges with index [1 − (1 / δ)] on the critical isobar, whe…

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1 John Stephenson Corresponding University of Alberta (CA) —

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