The photochemical reactions of the peroxide radicals in poly…
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- DOI 10.1002/polc.5070400103
- OpenAlex ID W2011556458
- Type Article
- Language EN
- Published 01 Jan 1973
- Volume 40 (1)
- Pages 1–8
- Source Journal of Polymer Science Polymer Sympo…
- Publisher Wiley
- Countries 1
- Institutions 1
- Added 10 Oct 2025
- Updated 22 Sep 2026
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The photochemical reactions of the peroxide radicals in polytetrafluorethylene
Article 1973 EN
Abstract The kinetics and mechanism of the photochemical reactions of the peroxide radicals have been investigated in polytetrafluorethylene by electron paramagnetic resonance. Under irradiation by UV light, with λ < 300 nm, the peroxide radicals ˜CF2 CF(O2)CF2∼ and ∼CF2 CF2 O2 are dissociated and the end fluoralkyl radicals ∼CF2 CF2 are produced. The activation effective energy of the photodissoc…
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2 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | Victor Konstantinovich Milinchuk | Karpov Institute of Physical C… (RU) | — |
| 2 | Edward Reyngol’dovich Klinshpont | Karpov Institute of Physical C… (RU) | — |
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